Ingredient Details :[(1S,1'R,3'R,4R,4'R,5S,5'R,6'R,12'S,13'S,16'R,18'S,21'R)-1,4',6',12',17',17'-hexamethyl-18'-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyspiro[3,6-dioxabicyclo[3.1.0]hexane-4,8'-9-oxahexacyclo[11.9.0.01,21.04,12.05,10.016,21]docosane]-3'-yl] acetate


TCMI-ID: TCMI21060


Physicochemical Property
Ingredient Name [(1S,1'R,3'R,4R,4'R,5S,5'R,6'R,12'S,13'S,16'R,18'S,21'R)-1,4',6',12',17',17'-hexamethyl-18'-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyspiro[3,6-dioxabicyclo[3.1.0]hexane-4,8'-9-oxahexacyclo[11.9.0.01,21.04,12.05,10.016,21]docosane]-3'-yl] acetate
Pubchem CID 101182169
Iupac name [(1S,1'R,3'R,4R,4'R,5S,5'R,6'R,12'S,13'S,16'R,18'S,21'R)-1,4',6',12',17',17'-hexamethyl-18'-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyspiro[3,6-dioxabicyclo[3.1.0]hexane-4,8'-9-oxahexacyclo[11.9.0.01,21.04,12.05,10.016,21]docosane]-3'-yl] acetate
Molecular Formula C37H56O10
Molecular Weight 660.8
Isomeric smiles C[C@@H]1C[C@]2([C@@H]3[C@@](O3)(CO2)C)OC4[C@H]1[C@]5([C@@H](C[C@@]67C[C@@]68CC[C@@H](C([C@@H]8CC[C@H]7[C@@]5(C4)C)(C)C)O[C@H]9[C@@H]([C@H]([C@@H](CO9)O)O)O)OC(=O)C)C
InChI InChI=1S/C37H56O10/c1-18-12-37(30-33(6,47-30)17-43-37)46-21-13-32(5)23-9-8-22-31(3,4)24(45-29-28(41)27(40)20(39)15-42-29)10-11-35(22)16-36(23,35)14-25(44-19(2)38)34(32,7)26(18)21/h18,20-30,39-41H,8-17H2,1-7H3/t18-,20-,21?,22+,23+,24+,25-,26+,27+,28-,29+,30+,32+,33+,34-,35-,36+,37-/m1/s1
InChIKey GCMGJWLOGKSUGX-DUGOAQORSA-N
External Database Links HERB2.0: HBIN004083  
Structural Information
nHA(Number of hydrogen bond acceptors) 10
nHD(Number of hydrogen bond donors) 3
nRot(Number of rotatable bonds) 4
nRing(Number of rings) 9
MaxRing(Number of atoms in the biggest ring) 22
nHet(Number of heteroatoms) 10

Stability
nRig(Number of rigid bonds) 41
Flexibility 0.098
Stereo Centers(Number of stereocenters) 18

Solubility
TPSA(Topological polar surface area) 136.44
logS(The logarithm of aqueous solubility value) -4.841
logP(The logarithm of the n-octanol/water distribution coefficient) 4.196
logD7.4(The logarithm of the n-octanol/water distribution coefficients at pH=7.4) 3.905

Pharmacokinetic Property
Quantitative Estimate of Drug-likeness 0.234
Synthetic accessibility score 6.924
Natural Product-likeness score 3.372
Lipinski Rule Accepted
GSK Rule Rejected
Golden Triangle Rejected

Absorption
Caco-2 Permeability -5.239
MDCK Permeability 2.01E-05
Pgp-substrate 0.007
HIA(human intestinal absorption) 0.003
F20%(20% Oral Bioavailability) 0.004
F30%(30% Oral Bioavailability) 0.189

Distribution
PPB(Plasma protein binding) 84.61%
VD(Volume Distribution) 0.858
BBB Penetration(Blood brain barrier penetration) 0.014
B3 Penetration(Blood brain barrier penetration) Non-Permeable
Fu(The fraction unbound in plasms) 11.24%

Metabolism
CYP1A2 inhibitor 0.002
CYP1A2 substrate 0.817
CYP2C19 inhibitor 0.008
CYP2C19 substrate 0.787
CYP2C9 inhibitor 0.078
CYP2C9 substrate 0.01
CYP2D6 inhibitor 0.006
CYP2D6 substrate 0.147
CYP3A4 inhibitor 0.525
CYP3A4 substrate 0.317

Excretion
CL(The clearance of a drug) 1.417
T1/2 0.664

Toxicology
NonBiodegradable Rule 2
Pfizer Rule Accepted
SR-MMP 0.776

Toxic Dose
FDAMDD(FDA Maximum (Recommended) Daily Dose) 0.888
IGC50 5.1
LC50FM 6.788
LC50DM 6.609

Reproductive Effects
NR-AR(Androgen receptor) 0.059
NR-AR-LBD(Androgen receptor) 0.988
NR-Aromatase 0.824
NR-ER(Estrogen receptor) 0.198
NR-ER-LBD(Estrogen receptor) 0.032

Allergy
Skin Sensitization Rule 4
Skin Sensitization 0.934

Acute Toxicity
Acute Toxicity Rule 4
Rat Oral Acute Toxicity 0.273

Organ Toxicity
hERG Blockers 0.261
H-HT(The human hepatotoxicity) 0.231
DILI(Drug-induced liver injury) 0.223

Primary Irritation
Eye Corrosion 0.004
Eye Irritation 0.016
Respiratory Toxicity 0.97

Mutagenic Effects
AMES Toxicity 0.811

Tumorigenic Effects
Carcinogencity 0.066
SR-ARE(Antioxidant Response Element) 0.053
SR-ATAD5(ATPase family AAA domain-containing protein 5) 0.841
SR-p53 0.992

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