Ingredient Details :Rotundioside O


TCMI-ID: TCMI16454


Physicochemical Property
Ingredient Name Rotundioside O
Pubchem CID 16097920
Iupac name (1S,2R,4S,5R,8R,10S,13S,14R,17S,18R)-10-[(2R,3R,4S,5R,6R)-3-[(2S,3R,4S,5S,6R)-4,5-dihydroxy-6-(hydroxymethyl)-3-[(2S,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyoxan-2-yl]oxy-4,5-dihydroxy-6-methyloxan-2-yl]oxy-2-hydroxy-4,5,9,9,13,20,20-heptamethyl-24-oxahexacyclo[15.5.2.01,18.04,17.05,14.08,13]tetracos-15-en-21-one
Molecular Formula C48H76O17
Molecular Weight 925.1
Isomeric smiles C[C@H]1[C@@H]([C@H]([C@H]([C@@H](O1)O[C@@H]2[C@H]([C@@H]([C@H](O[C@H]2O[C@@H]3[C@H]([C@H]([C@H](O[C@H]3O[C@H]4CC[C@]5([C@H](C4(C)C)CC[C@@]6([C@@H]5C=C[C@@]78[C@]6(C[C@H]([C@@]9([C@H]7CC(C(=O)C9)(C)C)CO8)O)C)C)C)C)O)O)CO)O)O)O)O)O
InChI InChI=1S/C48H76O17/c1-21-30(52)33(55)36(58)39(60-21)64-38-35(57)32(54)23(19-49)62-41(38)65-37-34(56)31(53)22(2)61-40(37)63-29-12-13-44(7)24(43(29,5)6)10-14-45(8)25(44)11-15-48-26-16-42(3,4)27(50)18-47(26,20-59-48)28(51)17-46(45,48)9/h11,15,21-26,28-41,49,51-58H,10,12-14,16-20H2,1-9H3/t21-,22+,23+,24-,25+,26+,28+,29-,30-,31-,32+,33+,34-,35-,36+,37+,38+,39-,40-,41-,44-,45+,46-,47+,48-/m0/s1
InChIKey RYKWBOUIIFTUAC-PGCPYQBQSA-N
External Database Links
Structural Information
nHA(Number of hydrogen bond acceptors) 17
nHD(Number of hydrogen bond donors) 9
nRot(Number of rotatable bonds) 7
nRing(Number of rings) 9
MaxRing(Number of atoms in the biggest ring) 19
nHet(Number of heteroatoms) 17

Stability
nRig(Number of rigid bonds) 48
Flexibility 0.146
Stereo Centers(Number of stereocenters) 25

Solubility
TPSA(Topological polar surface area) 263.75
logS(The logarithm of aqueous solubility value) -4.226
logP(The logarithm of the n-octanol/water distribution coefficient) 2.626
logD7.4(The logarithm of the n-octanol/water distribution coefficients at pH=7.4) 2.308

Pharmacokinetic Property
Quantitative Estimate of Drug-likeness 0.127
Synthetic accessibility score 7.705
Natural Product-likeness score 2.585
Lipinski Rule Rejected
GSK Rule Rejected
Golden Triangle Rejected

Absorption
Caco-2 Permeability -6.13
MDCK Permeability 7.87E-05
Pgp-substrate 0.999
HIA(human intestinal absorption) 0.95
F20%(20% Oral Bioavailability) 0.105
F30%(30% Oral Bioavailability) 0.999

Distribution
PPB(Plasma protein binding) 61.29%
VD(Volume Distribution) 0.298
BBB Penetration(Blood brain barrier penetration) 0.037
B3 Penetration(Blood brain barrier penetration) Non-Permeable
Fu(The fraction unbound in plasms) 15.54%

Metabolism
CYP1A2 inhibitor 0
CYP1A2 substrate 0.908
CYP2C19 inhibitor 0.002
CYP2C19 substrate 0.538
CYP2C9 inhibitor 0.002
CYP2C9 substrate 0.006
CYP2D6 inhibitor 0.002
CYP2D6 substrate 0.071
CYP3A4 inhibitor 0.17
CYP3A4 substrate 0.048

Excretion
CL(The clearance of a drug) 0.716
T1/2 0.714

Toxicology
NonBiodegradable Rule 2
Pfizer Rule Accepted
SR-MMP 0.957

Toxic Dose
FDAMDD(FDA Maximum (Recommended) Daily Dose) 0.852
IGC50 4.748
LC50FM 6.381
LC50DM 6.861

Reproductive Effects
NR-AR(Androgen receptor) 0.143
NR-AR-LBD(Androgen receptor) 0.475
NR-Aromatase 0.857
NR-ER(Estrogen receptor) 0.456
NR-ER-LBD(Estrogen receptor) 0.458

Allergy
Skin Sensitization Rule 2
Skin Sensitization 0.016

Acute Toxicity
Acute Toxicity Rule 3
Rat Oral Acute Toxicity 0.217

Organ Toxicity
hERG Blockers 0.085
H-HT(The human hepatotoxicity) 0.245
DILI(Drug-induced liver injury) 0.01

Primary Irritation
Eye Corrosion 0.003
Eye Irritation 0.006
Respiratory Toxicity 0.989

Mutagenic Effects
AMES Toxicity 0.064

Tumorigenic Effects
Carcinogencity 0.027
SR-ARE(Antioxidant Response Element) 0.199
SR-ATAD5(ATPase family AAA domain-containing protein 5) 0.837
SR-p53 0.971

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