Ingredient Details :Cimicifugoside H1


TCMI-ID: TCMI16167


Physicochemical Property
Ingredient Name Cimicifugoside H1
Pubchem CID 15241163
Iupac name (1S,3R,6S,8R,12R,15R,16R,18S)-15-[(2R)-4-[(2R)-3,3-dimethyloxiran-2-yl]-4-oxobutan-2-yl]-18-hydroxy-7,7,12,16-tetramethyl-6-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxypentacyclo[9.7.0.01,3.03,8.012,16]octadec-10-en-14-one
Molecular Formula C35H52O9
Molecular Weight 616.8
Isomeric smiles C[C@H](CC(=O)[C@H]1C(O1)(C)C)[C@H]2C(=O)C[C@@]3([C@@]2(C[C@@H]([C@]45C3=CC[C@@H]6[C@]4(C5)CC[C@@H](C6(C)C)O[C@H]7[C@@H]([C@H]([C@@H](CO7)O)O)O)O)C)C
InChI InChI=1S/C35H52O9/c1-17(12-18(36)28-31(4,5)44-28)25-19(37)13-32(6)22-9-8-21-30(2,3)24(43-29-27(41)26(40)20(38)15-42-29)10-11-34(21)16-35(22,34)23(39)14-33(25,32)7/h9,17,20-21,23-29,38-41H,8,10-16H2,1-7H3/t17-,20-,21+,23+,24+,25+,26+,27-,28+,29+,32+,33-,34-,35+/m1/s1
InChIKey PYBFXJMIKJNNAJ-GLWILYKISA-N
External Database Links SymMap: SMIT12869  
Structural Information
nHA(Number of hydrogen bond acceptors) 9
nHD(Number of hydrogen bond donors) 4
nRot(Number of rotatable bonds) 6
nRing(Number of rings) 7
MaxRing(Number of atoms in the biggest ring) 18
nHet(Number of heteroatoms) 9

Stability
nRig(Number of rigid bonds) 33
Flexibility 0.182
Stereo Centers(Number of stereocenters) 14

Solubility
TPSA(Topological polar surface area) 146.05
logS(The logarithm of aqueous solubility value) -4.448
logP(The logarithm of the n-octanol/water distribution coefficient) 3.353
logD7.4(The logarithm of the n-octanol/water distribution coefficients at pH=7.4) 3.099

Pharmacokinetic Property
Quantitative Estimate of Drug-likeness 0.261
Synthetic accessibility score 6.57
Natural Product-likeness score 3.149
Lipinski Rule Accepted
GSK Rule Rejected
Golden Triangle Rejected

Absorption
Caco-2 Permeability -5.215
MDCK Permeability 9.68E-06
Pgp-substrate 0.732
HIA(human intestinal absorption) 0.022
F20%(20% Oral Bioavailability) 0.945
F30%(30% Oral Bioavailability) 0.95

Distribution
PPB(Plasma protein binding) 77.92%
VD(Volume Distribution) 0.595
BBB Penetration(Blood brain barrier penetration) 0.044
B3 Penetration(Blood brain barrier penetration) Permeable
Fu(The fraction unbound in plasms) 15.04%

Metabolism
CYP1A2 inhibitor 0.001
CYP1A2 substrate 0.339
CYP2C19 inhibitor 0.008
CYP2C19 substrate 0.831
CYP2C9 inhibitor 0.038
CYP2C9 substrate 0.048
CYP2D6 inhibitor 0.003
CYP2D6 substrate 0.155
CYP3A4 inhibitor 0.432
CYP3A4 substrate 0.305

Excretion
CL(The clearance of a drug) 2.38
T1/2 0.688

Toxicology
NonBiodegradable Rule 3
Pfizer Rule Accepted
SR-MMP 0.952

Toxic Dose
FDAMDD(FDA Maximum (Recommended) Daily Dose) 0.941
IGC50 4.598
LC50FM 6.824
LC50DM 6.666

Reproductive Effects
NR-AR(Androgen receptor) 0.853
NR-AR-LBD(Androgen receptor) 0.962
NR-Aromatase 0.904
NR-ER(Estrogen receptor) 0.294
NR-ER-LBD(Estrogen receptor) 0.017

Allergy
Skin Sensitization Rule 3
Skin Sensitization 0.19

Acute Toxicity
Acute Toxicity Rule 5
Rat Oral Acute Toxicity 0.945

Organ Toxicity
hERG Blockers 0.022
H-HT(The human hepatotoxicity) 0.263
DILI(Drug-induced liver injury) 0.083

Primary Irritation
Eye Corrosion 0.003
Eye Irritation 0.009
Respiratory Toxicity 0.956

Mutagenic Effects
AMES Toxicity 0.514

Tumorigenic Effects
Carcinogencity 0.057
SR-ARE(Antioxidant Response Element) 0.092
SR-ATAD5(ATPase family AAA domain-containing protein 5) 0.889
SR-p53 0.951

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