Ingredient Details :methyl (Z)-6-[(10S,13R,17S)-3,15-dihydroxy-4,4,10,13,14,17-hexamethyl-7,11-dioxo-1,2,3,5,6,12,15,16-octahydrocyclopenta[a]phenanthren-17-yl]-2-methyl-4-oxohept-5-enoate


TCMI-ID: TCMI10055


Physicochemical Property
Ingredient Name methyl (Z)-6-[(10S,13R,17S)-3,15-dihydroxy-4,4,10,13,14,17-hexamethyl-7,11-dioxo-1,2,3,5,6,12,15,16-octahydrocyclopenta[a]phenanthren-17-yl]-2-methyl-4-oxohept-5-enoate
Pubchem CID 5319661
Iupac name methyl (Z)-6-[(10S,13R,17S)-3,15-dihydroxy-4,4,10,13,14,17-hexamethyl-7,11-dioxo-1,2,3,5,6,12,15,16-octahydrocyclopenta[a]phenanthren-17-yl]-2-methyl-4-oxohept-5-enoate
Molecular Formula C32H46O7
Molecular Weight 542.7
Isomeric smiles CC(CC(=O)/C=C(/C)\[C@@]1(CC(C2([C@@]1(CC(=O)C3=C2C(=O)CC4[C@@]3(CCC(C4(C)C)O)C)C)C)O)C)C(=O)OC
InChI InChI=1S/C32H46O7/c1-17(27(38)39-9)12-19(33)13-18(2)30(6)16-24(37)32(8)26-20(34)14-22-28(3,4)23(36)10-11-29(22,5)25(26)21(35)15-31(30,32)7/h13,17,22-24,36-37H,10-12,14-16H2,1-9H3/b18-13-/t17?,22?,23?,24?,29-,30-,31+,32?/m0/s1
InChIKey LHWMZHJFDMVPPP-ZPTOFWMHSA-N
External Database Links HERB2.0: HBIN035236   TCMSID: 15497  
Structural Information
nHA(Number of hydrogen bond acceptors) 7
nHD(Number of hydrogen bond donors) 2
nRot(Number of rotatable bonds) 6
nRing(Number of rings) 4
MaxRing(Number of atoms in the biggest ring) 17
nHet(Number of heteroatoms) 7

Stability
nRig(Number of rigid bonds) 25
Flexibility 0.24
Stereo Centers(Number of stereocenters) 8

Solubility
TPSA(Topological polar surface area) 117.97
logS(The logarithm of aqueous solubility value) -4.811
logP(The logarithm of the n-octanol/water distribution coefficient) 3.051
logD7.4(The logarithm of the n-octanol/water distribution coefficients at pH=7.4) 2.673

Pharmacokinetic Property
Quantitative Estimate of Drug-likeness 0.387
Synthetic accessibility score 5.332
Natural Product-likeness score 2.104
Lipinski Rule Accepted
GSK Rule Rejected
Golden Triangle Rejected

Absorption
Caco-2 Permeability -5.211
MDCK Permeability 2.14E-05
Pgp-substrate 0.01
HIA(human intestinal absorption) 0.03
F20%(20% Oral Bioavailability) 0.023
F30%(30% Oral Bioavailability) 0.663

Distribution
PPB(Plasma protein binding) 78.49%
VD(Volume Distribution) 0.406
BBB Penetration(Blood brain barrier penetration) 0.764
B3 Penetration(Blood brain barrier penetration) Non-Permeable
Fu(The fraction unbound in plasms) 18.75%

Metabolism
CYP1A2 inhibitor 0.003
CYP1A2 substrate 0.648
CYP2C19 inhibitor 0.082
CYP2C19 substrate 0.894
CYP2C9 inhibitor 0.062
CYP2C9 substrate 0.031
CYP2D6 inhibitor 0.002
CYP2D6 substrate 0.041
CYP3A4 inhibitor 0.814
CYP3A4 substrate 0.851

Excretion
CL(The clearance of a drug) 11.832
T1/2 0.066

Toxicology
NonBiodegradable Rule 1
Pfizer Rule Accepted
SR-MMP 0.902

Toxic Dose
FDAMDD(FDA Maximum (Recommended) Daily Dose) 0.922
IGC50 4.852
LC50FM 4.045
LC50DM 4.439

Reproductive Effects
NR-AR(Androgen receptor) 0.335
NR-AR-LBD(Androgen receptor) 0.753
NR-Aromatase 0.815
NR-ER(Estrogen receptor) 0.146
NR-ER-LBD(Estrogen receptor) 0.677

Allergy
Skin Sensitization Rule 4
Skin Sensitization 0.11

Acute Toxicity
Acute Toxicity Rule 3
Rat Oral Acute Toxicity 0.155

Organ Toxicity
hERG Blockers 0.012
H-HT(The human hepatotoxicity) 0.403
DILI(Drug-induced liver injury) 0.159

Primary Irritation
Eye Corrosion 0.003
Eye Irritation 0.008
Respiratory Toxicity 0.974

Mutagenic Effects
AMES Toxicity 0.055

Tumorigenic Effects
Carcinogencity 0.558
SR-ARE(Antioxidant Response Element) 0.92
SR-ATAD5(ATPase family AAA domain-containing protein 5) 0.781
SR-p53 0.94

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