Ingredient Details :Butanoic acid, 3-(acetyloxy)-3-methyl-, 1-(1,4-dihydro-5,8-dihydroxy-1,4-dioxo-2-naphthalenyl)-4-methyl-3-pentenyl ester, (S)-


TCMI-ID: TCMI04509


Physicochemical Property
Ingredient Name Butanoic acid, 3-(acetyloxy)-3-methyl-, 1-(1,4-dihydro-5,8-dihydroxy-1,4-dioxo-2-naphthalenyl)-4-methyl-3-pentenyl ester, (S)-
Pubchem CID 155245
Iupac name [(1S)-1-(5,8-dihydroxy-1,4-dioxonaphthalen-2-yl)-4-methylpent-3-enyl] 3-acetyloxy-3-methylbutanoate
Molecular Formula C23H26O8
Molecular Weight 430.4
Isomeric smiles CC(=CC[C@@H](C1=CC(=O)C2=C(C=CC(=C2C1=O)O)O)OC(=O)CC(C)(C)OC(=O)C)C
InChI InChI=1S/C23H26O8/c1-12(2)6-9-18(30-19(28)11-23(4,5)31-13(3)24)14-10-17(27)20-15(25)7-8-16(26)21(20)22(14)29/h6-8,10,18,25-26H,9,11H2,1-5H3/t18-/m0/s1
InChIKey BQSAGDWOHVQNFB-SFHVURJKSA-N
External Database Links
Structural Information
nHA(Number of hydrogen bond acceptors) 8
nHD(Number of hydrogen bond donors) 2
nRot(Number of rotatable bonds) 9
nRing(Number of rings) 2
MaxRing(Number of atoms in the biggest ring) 10
nHet(Number of heteroatoms) 8

Stability
nRig(Number of rigid bonds) 16
Flexibility 0.562
Stereo Centers(Number of stereocenters) 1

Solubility
TPSA(Topological polar surface area) 127.2
logS(The logarithm of aqueous solubility value) -4.691
logP(The logarithm of the n-octanol/water distribution coefficient) 4.451
logD7.4(The logarithm of the n-octanol/water distribution coefficients at pH=7.4) 2.897

Pharmacokinetic Property
Quantitative Estimate of Drug-likeness 0.383
Synthetic accessibility score 3.701
Natural Product-likeness score 2.114
Lipinski Rule Accepted
GSK Rule Rejected
Golden Triangle Accepted

Absorption
Caco-2 Permeability -4.689
MDCK Permeability 3.40E-05
Pgp-substrate 0.003
HIA(human intestinal absorption) 0.285
F20%(20% Oral Bioavailability) 0.184
F30%(30% Oral Bioavailability) 0.986

Distribution
PPB(Plasma protein binding) 92.06%
VD(Volume Distribution) 0.823
BBB Penetration(Blood brain barrier penetration) 0.026
B3 Penetration(Blood brain barrier penetration) Non-Permeable
Fu(The fraction unbound in plasms) 7.90%

Metabolism
CYP1A2 inhibitor 0.924
CYP1A2 substrate 0.082
CYP2C19 inhibitor 0.82
CYP2C19 substrate 0.063
CYP2C9 inhibitor 0.903
CYP2C9 substrate 0.902
CYP2D6 inhibitor 0.87
CYP2D6 substrate 0.132
CYP3A4 inhibitor 0.681
CYP3A4 substrate 0.169

Excretion
CL(The clearance of a drug) 9.155
T1/2 0.203

Toxicology
NonBiodegradable Rule 1
Pfizer Rule Accepted
SR-MMP 0.98

Toxic Dose
FDAMDD(FDA Maximum (Recommended) Daily Dose) 0.914
IGC50 5.582
LC50FM 6.788
LC50DM 6.979

Reproductive Effects
NR-AR(Androgen receptor) 0.008
NR-AR-LBD(Androgen receptor) 0.613
NR-Aromatase 0.554
NR-ER(Estrogen receptor) 0.544
NR-ER-LBD(Estrogen receptor) 0.925

Allergy
Skin Sensitization Rule 9
Skin Sensitization 0.773

Acute Toxicity
Acute Toxicity Rule 3
Rat Oral Acute Toxicity 0.91

Organ Toxicity
hERG Blockers 0.008
H-HT(The human hepatotoxicity) 0.692
DILI(Drug-induced liver injury) 0.875

Primary Irritation
Eye Corrosion 0.014
Eye Irritation 0.103
Respiratory Toxicity 0.948

Mutagenic Effects
AMES Toxicity 0.937

Tumorigenic Effects
Carcinogencity 0.814
SR-ARE(Antioxidant Response Element) 0.938
SR-ATAD5(ATPase family AAA domain-containing protein 5) 0.498
SR-p53 0.979

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